Mineral Species: Pharmacosiderite
Chemical Formula: KFe4(AsO4(OH)4 - 7H2O
Chemical Name: Hydrated Potassium Iron Arsenate Hydroxide
Mineral Class: Arsenate
Mineral Notes: Pharmacosiderite is a rare secondary arsenate mineral. It typically forms in the oxidation zones of iron ore deposits from the alteration of Arsenopyrite, Tennantite and other primary arsenic minerals, and less often, directly from precipitation of hydrothermal solutions. The mineral forms cubic crystals. This is extremely unusual for an arsenate or even a phosphate. Occasionally, Pharmacosiderite can be confused with Fluorite but the latter has perfect cleavage and is harder. The mineral should not be confused with Siderite, which is a simple iron carbonate. Pharmacosiderite lends its name to a small mineral group called the Pharmacosiderite Group. These are a set of closely related arsenates of which pharmacosiderite is the most common member. Others in the group include Alumopharmacosiderite and Sodiumpharmacosiderite.
Description: Crystalline, dark-green Pharmacosiderite on matrix. Under magnification the cubic crystal form is easily seen. Many of the crystals are twinned and together with good transparency the mineral does resemble crystalline Fluorite. However the green colour makes the mineral quite distinct. A very nice specimen from a classic location.
Location: Wheat Gorland, St Day, Cornwall, England.
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